Condensation in Dust-enriched Systems, by D.S. Ebel and L. Grossman,
Geochimica et Cosmochimica Acta, 1999

Technique: Bulk Composition

The nature of the condensates from dust-enriched bulk compositions is strongly influenced by the composition assumed for the dust, and an infinite variety of fractionated dust compositions can be imagined. One constraint on dust composition, however, is that it lead to condensate assemblages containing chondritic proportions of condensable elements. C1 chondrites are representative of the bulk composition of the condensable fraction of solar system matter. If the bulk of the condensable elements was originally brought to the solar nebula in the form of interstellar dust, then it is reasonable to assume that the aggregate composition of that dust had a bulk chemical composition similar to that of C1 chondrites. Table 1 shows the relative atomic abundances of the 23 elements considered in this work in solar gas (Anders and Grevesse, 1989), the C1 chondrite dust component of solar gas, and several dust-enriched systems. For a dust enrichment of n, one way to calculate the bulk composition is by adding (n-1) units of the C1 dust to solar composition. Enrichment factors of up to 1000 were investigated. Although there are as yet no astronomical observations that confirm, or astrophysical models that produce, such enrichments, there exists no evidence to rule out such enrichments in protoplanetary environments.

Table 1. Relative atomic abundances in solar composition and the C1 component of solar composition, both normalized to 106 atoms Si, and compositions of systems enriched in dust of C1 composition relative to solar.

Table 1. Relative atomic abundances in solar composition and the C1 component of solar composition, both normalized to 106 atoms Si, and compositions of systems enriched in dust of C1 composition relative to solar.
 

Solar

Cl Dust

100 x Cl

500 x Cl

1000 x Cl

H

2.79 x 1010

5.28 x 106

2.84 x 1010

3.05 x 1010

3.32 x 1010

He

2.72 x 109

 

2.72 x 109

2.72 x 109

2.72 x 109

C

1.01 x 107

7.56 x 105

8.50 x 107

3.87 x 108

7.65 x 108

N

3.13 x 106

5.98 x 104

9.05 x 106

3.30 x 107

6.28 x 107

O

2.38 x 107

7.63 x 106

7.80 x 108

3.83 x 109

7.65 x 109

F

8.43 x 102

8.43 x 102

8.43 x 104

4.22 x 105

8.43 x 105

Ne

3.44 x 106

 

3.44 x 106

3.44 x 106

3.44 x 106

Na

5.74 x 104

5.74 x 104

5.74 x 106

2.87 x 107

5.74 x 107

Mg

1.07 x 106

1.07 x 106

1.07 x 108

5.37 x 108

1.07 x 109

Al

8.49 x 104

8.49 x 104

8.49 x 106

4.25 x 107

8.49 x 107

Si

1.00 x 106

1.00 x 106

1.00 x 108

5.00 x 108

1.00 x 109

P

1.04 x 104

1.04 x 104

1.04 x 106

5.20 x 106

1.04 x 107

S

5.15 x 105

5.15 x 105

5.15 x 107

2.58 x 108

5.15 x 108

Cl

5.24 x 103

5.24 x 103

5.24 x 105

2.62 x 106

5.24 x 106

Ar

1.01 x 105

 

1.01 x 105

1.01 x 105

1.01 x 105

K

3.77 x 103

3.77 x 103

3.77 x 105

1.89 x 106

3.77 x 106

Ca

6.11 x 104

6.11 x 104

6.11 x 106

3.06 x 107

6.11 x 107

Ti

2.40 x 103

2.40 x 103

2.40 x 105

1.20 x 106

2.40 x 106

Cr

1.35 x 104

1.35 x 104

1.35 x 106

6.75 x 106

1.35 x 107

Mn

9.55 x 103

9.55 x 103

9.55 x 105

4.78 x 106

9.55 x 106

Fe

9.00 x 105

9.00 x 105

9.00 x 107

4.50 x 108

9.00 x 108

Co

2.25 x 103

2.25 x 103

2.25 x 105

1.13 x 106

2.25 x 106

Ni

4.93 x 104

4.93 x 104

4.93 x 106

2.47 x 107

4.93 x 107



CONDENSATION
in
DUST-ENRICHED SYSTEMS


Denton S. Ebel (1)

Lawrence Grossman(1,2)

(1) Department of The Geophysical Sciences
The University of Chicago
5734 South Ellis Ave.
Chicago, IL 60637

(2) Enrico Fermi Institute
The University of Chicago
5640 South Ellis Ave.
Chicago, IL 60637

Submitted December 22, 1998 to

Geochimica et Cosmochimica Acta

Revised version submitted June 30, 1999
Abstract Introduction
Technique

Bulk Composition
Method of Calculation
Data for Elements and Gas Species
Data and Models for Solids
Data and Models for Silicate Liquids
Test of MELTS: Peridotite KLB-1
Transition Between Liquid Models
Results

Vapor of Solar Composition
General Effects of Dust Enrichment and Total Pressure
Oxygen Fugacity
Condensation Temperatures and Liquid Stability
Condensation at 100x Dust Enrichment, Ptot=10-3bar
Condensation at 1000x Dust Enrichment, Ptot=10-3bar
Condensation of Oxidized Iron at High Temperature
Bulk Chemical Composition of Condensates
Composition of Silicate Liquid
Composition of Spinel
Composition of Clinopyroxene
Composition of Feldspar
Composition of Metallic Nickel-Iron
Metal-Sulfide Condensate Assemblages
Discussion

Stability of Silicate Liquid in Solar Gas
Chondrules in Dust-enriched Systems
Conclusions References